• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Extrusion plant for the production of a coextruded P-profile for tires made from rubber mixtures of different compositions, comprising a profiling device (30) arranged at the outlet of at least two flow channels (34, 35) of rubber mixes of different composition. According to the invention, said channels receive the mixtures coming from twin-screw extruders (10,20) counter-rotating interpenetrated nets and conjugated profiles.
    公开号:FR3045441A1
    申请号:FR1563085
    申请日:2015-12-22
    公开日:2017-06-23
    发明作者:Arnaud Letocart；Christophe Ougier
    申请人:Michelin Recherche et Technique SA Switzerland ；Compagnie Generale des Etablissements Michelin SCA；Michelin Recherche et Technique SA France；
    IPC主号:
    专利说明:

    INSTALLATION AND METHOD FOR EXTRUDING MIXTURES OF
    RUBBER
    [001] The invention relates to the field of extrusion of rubber mixtures more particularly intended for the manufacture of tires. More particularly, it relates to the production coextruded profiled based on rubber mixtures of different compositions.
    In a known manner, an installation for manufacturing complex profiles by extrusion of at least two rubber mixtures of different compositions, or coextrusion, comprises at least two extruders. Each extruder is formed of a cylindrical body or sleeve which is fixed inside which there is a screw coaxial with the longitudinal axis of the sleeve and driven in rotation around it. Its function is to homogenize and push a rubbery mixture towards an outlet orifice. For a complex product, the outlet port receives several rubber mixtures of different compositions and defines the profile of the rubber band. This profile is defined by a fixed profiled blade or a fixed profiled wall cooperating with a rotating roller.
    [003] The manufacture of tires is increasingly called upon the use of complex products to reduce the number of product poses in assembly and thus reduce the cost and increase the accuracy.
    [004] The number of different rubber mixes used to manufacture a single tire tends to increase so as to increase the properties of the tire depending on the area in which these mixtures are located. For example, in a tire tread which generally included two different rubber compounds, other mixtures are nowadays added, for example an electrically conductive mixture and mixtures intended to cover the sidewalls at the shoulders.
    During a production by coextrusion, the mixtures are converged to the outlet orifice which makes it possible to bond raw, pressure and temperature mixtures without contact in the open air and before profiling. This makes it possible to obtain good behavior of the coextruded product at the interfaces between the mixtures. However, because the rheological properties differ from one mixture to another, it is difficult to perfectly control the geometry of the assembly, in particular being the difficulty of positioning a product of a certain mixture by report to another.
    The positioning of a product relative to another is given by a profiling device in which the different mixtures from different extruders arrive to form the complex section coextruded output. In practice, the geometric shape and the dimensions of the profiling device are determined by several successive iteration loops. Once the device has been developed, it only gives the expected results when the extruders operate continuously and at a specific speed.
    [007] The non-compliant coextruded profile currently represents a significant part of the production of the machine. The shorter the runs for flexible production, the higher the fall rates (5% to 20% in practice). This results in a decrease in the profitability of the machine. In addition, the losses of material being economically unacceptable, so-called mixed falls (or multi-compounds) must be stored, rehomogenized and reintroduced in a controlled way, precisely dosed, in the following productions. The extra manufacturing cost that this entails is accompanied, in addition, by a drop in the performance of the finally obtained product which is partly polluted by the other mixtures.
    Furthermore, the product coextruded continuously, by measuring the linear weight of the outgoing product and comparing it to a preset weight. In addition, the shape and dimensions of the complex product (width, thickness) are evaluated using different sensors.
    Thus discloses WO 2015/028166 which describes a pneumatic tread manufacturing method by coextrusion of different mixtures from several extruders arranged in parallel, in which the transverse profile is analyzed by contactless sensors. . The profile of each part constituting the band is read by a sensor, the profiles being then analyzed by a central control unit which controls the operation of each extruder. The adjustment of the operation of an extruder is done by adjusting the speed of rotation of the screw and the pressure at the end of the screw, just before the exit. However, its operation also depends on the thermal regime of the mixture, the thermal regime of the die, the extrusion rate, the rheology of the mixture, the disruption of the feeding of the band, etc. . All of these factors interfere with extruder throughput, so many adjustments are needed before a compliant product is obtained.
    [010] Moreover, the measurements performed with optical sensors are not sufficient, however, to guarantee the correct positioning within the complex product of the various constituents, one with respect to the other, nor to visualize their respective interfaces. especially when they are superimposed. As a result, a final check is done by taking samples. Samples taken during all these developments can not be recycled because it is a composite and they are discarded, which generates losses of material and increases the overall cost of the products obtained.
    Also known is US5725814 which describes an arrangement of several extruders each having an output gear pump to produce a complex product based on different plastics. Such an arrangement makes it possible to use a regulation based on the adjustment of the speed of the pump to vary the proportion of one material with respect to another during the manufacture of the complex. The major disadvantage of such a solution is the large size of the gear pump, which directly impacts the size of the formatting tool, and all the more so when the number of channels is greater than two. . The tools are then expensive, difficult to handle and the thermal regime is longer.
    The object of the invention is to overcome these disadvantages.
    [013] This objective is achieved with an extrusion installation for the manufacture of a coextruded P profile for tires made from rubber mixtures of different compositions, comprising a profiling device arranged at the output of at least two channels. process for the flow of rubber mixes of different composition, characterized in that said channels receive mixtures from twin-screw contrarotative extruders with interpenetrating nets and conjugate profiles.
    [014] The extrusion plant of the invention comprises at least two contra-rotating twin-screw extruders interpenetrated nets and conjugate profiles that can accurately convey two different mixtures in flow channels that open into a device. profiling to achieve a complex profile by coextrusion. This produces a coextruded profile product, by superposition of different mixtures during the passage through the profiling device, which has a precise profile and repeatable over time.
    [015] More particularly, each twin-screw extruder comprises two screws whose threads interpenetrate and have conjugate profiles, the screw being rotated in opposite directions which allows to convey the mixture in two closed and delimited C chambers by the space between each screw and the sheath. The advancement of the chambers is the value of the thread pitch per revolution of rotation of the screw, which allows a constant flow, which is independent of the coefficient of friction of the mixture on the walls of the sleeve and frees therefore, factors such as the rheology of the mixture, its pressure, its temperature, etc. This makes it easy to adjust the flow rate by adjusting the speed of each extruder, ensuring stable and repetitive operation of the plant.
    [016] Thus, as for each component of the coextruded profile, the geometric shape is given by the profiling device and the flow of the mixture is given by the conveying extruder of the mixture to the device, using a twin-screw extruder to supply each channel or flow channel leading to the profiling device, a coextruded profile having a good accuracy of its geometrical shape and its dimensions is obtained from the first lengths of extruded profile strip.
    [017] According to the invention, said twin-screw extruders are arranged in such a way that each delivers directly into a flow channel. This provides a multi-channel profiling device having an optimized value of the section in the extrusion direction. Indeed, the height of the inlet section in the flow channels in which the two mixtures that arrive in the extrusion direction open is very small for a maximum value of the flow rate provided by the twin-screw extruders. In addition, the mixture does not change direction, which minimizes the swelling of the coextruded product.
    [018] Advantageously, each twin-screw extruder is fed by a secondary extruder single screw.
    It is also possible to use another unit for plasticizing the mixture upstream of twin-screw extruders, such as a twin-screw mixer. However, it is preferred to use an extruder because it allows to feed the chambers of the twin-screw extruder with fluidized and homogenized mixture. The extruder can thus be provided with homogenizing fingers when it is desired to provide even more work to the mixture.
    [020] Preferably, the twin-screw extruder and the secondary extruder are arranged in a common housing.
    This allows a direct transfer of the plasticized mixture from the secondary extruder to the twin screw extruder, without using additional devices and actuators, which complicates the construction and increases the price of the installation.
    [022] Advantageously, the secondary extruder has an outlet end which communicates with a central inlet orifice in an internal chamber of the twin-screw extruder.
    [023] This allows to feed mixture in a balanced manner, via an inlet port placed along the median longitudinal axis of the twin-screw extruder.
    [024] Preferably, the twin-screw extruder and the secondary extruder each comprise its own drive means.
    [025] In a variant, a rotation drive means common to both extruders is used because it is more economical. However, it is preferred to drive each extruder by independent means so as to independently adjust the operating parameters of each.
    [026] Advantageously, the axis of rotation of the screw of the secondary extruder is transverse to the axis of rotation of the screws of the twin-screw extruder.
    [027] Such an arrangement of extruders with perpendicular axes provides a compact assembly of small size. It is thus possible to feed several channels of the profiling device in parallel with such sets of extruders.
    [028] Preferably, the installation comprises a control unit provided for adjusting the speed of rotation of the screws of said twin-screw extruders as a function of the dimensions of the coextruded profile.
    [029] The twin-screw extruder has a known intrinsic flow rate which is proportional to its rotational speed. The control unit makes it possible to adapt it to the dimensions of the coextruded profile. In a variant, a weight sensor connected to the control unit continuously measures the weight of the coextruded profile, which makes it possible to finely adjust the weight per meter of the profile.
    [030] Advantageously, said control unit adjusts the rotational speed of the screws of said twin-screw extruders to adapt to the operating conditions of a related assembly line.
    [031] The installation of the invention is particularly advantageous in the case of the preparation of coextruded profile which is integrated in the assembly. In this case, the running speed of the product is variable, because it depends on that of the assembly line, and the operation is brought to alternate the phases of operation with those of stopping the installation. This adjusts the operation of the installation to that of the assembly line simply by controlling the speeds of twin-screw extruders.
    [032] The objects of the invention are also achieved with a method of manufacturing a coextruded P profile for tires made from rubber mixtures of different compositions by extrusion passing through a profiling tool from two channels. mixing flow, characterized in that it comprises a step of supplying said channels made by twin-screw contrarotative extruders interpenetrated nets and conjugate profiles.
    [033] Advantageously, the method of the invention comprises a step of adjusting the rotational speed of the screws of the twin-screw extruder according to the dimensions of the coextruded profile P.
    [034] Preferably, the flow rate provided by each twin-screw extruder is greater than 20 kg / min for a speed less than or equal to 40 rpm. This allows good productivity for low speeds of rotation while avoiding heating of the mixture.
    [035] The following description is based on Figures 1 to 6 wherein: Figure 1 schematically illustrates in perspective an extrusion plant according to an embodiment of the invention; Figure 2 is a sectional view taken with a plane passing through the longitudinal axis X-X 'of the secondary extruder (40); FIGS. 3a and 3b illustrate, by sectional views, exemplary embodiments of the screws which are fitted to the extruders vi-screw of the installation of the invention; Figure 4 is a sectional view taken with a plane containing the longitudinal axes of the twin-screw extruder screws; Figure 5 is an enlarged view of a portion of the installation of Figure 1; Figure 6 is a schematic sectional view of a profiling device fed by extruders according to the state of the art.
    [036] The extrusion plant shown in Figure 1 comprises a first secondary extruder 40 and a second secondary extruder 50 which are extruders with an Archimedean screw. These extruders are each provided, at an inlet end 42, respectively 52, a feed hopper 41, respectively 51, a mixture of raw rubber A and B, the two mixtures having different compositions. Each secondary extruder 40, 50 comprises a screw 45, 55 driven in rotation about its longitudinal axis X-X ', Y-Y', by a geared motor 44, 54 inside a sheath of circular section 46, 56 Each rubber mixture A, B is mixed, pressurized and temperature, homogenized before reaching the exit end 43, 53 of the extruder.
    [037] The extrusion installation also comprises a profiling device 30 having an extrusion orifice 31, whose cross section gives the geometric shape to the coextruded profile. For this purpose, the profiling device comprises an upper arch 36 and a lower arch 37 defining with an intermediate support 38 two flow channels 34, 35 each of one of the mixtures A and B coming from the extruder 40 and Extruder 50. The channels 34 and 35 open on the same extrusion orifice 31 through which the two mixtures A and B are discharged. The extrusion orifice 31 is delimited by the walls of the profiling device 30 and makes it possible to confer on the assembly constituted by the coextruded mixtures the desired profile.
    [038] According to the invention, the extrusion plant comprises twin-screw extruders 10, 20 arranged between the secondary extruders 40, 50 and the profiling device 30. The twin-screw extruders are counter-rotating type interpenetrated nets and conjugate profiles, and are arranged to open each directly into the flow channel 34, respectively 35 profiling device 30. Each bi-screw extruder 10, 20 is fed by a secondary extruder 40, 50, the end 46, 56 of the latter being in communication with an inlet port in an internal chamber of the twin-screw extruder. The extruder 10 comprises two screws 11, 12 each rotating about a longitudinal axis parallel to that of the flow channel 34. The extruder 20 comprises two screws 21, 22 each rotating about a longitudinal axis parallel to that of the flow channel 35.
    [039] A twin-screw extruder has a high compactness for a given flow rate at a given temperature. Thus, a twin-screw extruder used in the installation of the invention has a diameter d of each screw 11,12 or 21,22 of 100 mm, a notching rate (it is understood the ratio between the diameter of the part and the external diameter of the screw) close to 50%, a length ratio L / d diameter equal to 4, a pitch equal to 100mm, for a flow rate of about 22 kg / min at a speed of about 40 tr / min.
    [040] This is not the case of a gear pump extruder of the state of the art. To better highlight this difference, there is illustrated in Figure 6 a coextrusion installation that would use gear pumps of the state of the art. When comparing the solution of the invention, as visible in FIG. 4 and a gear pump installation of the state of the art (FIG 6), it is observed that for an equivalent space "h" (the height of the inlet section in the flow channels in which open both mixtures in the extrusion direction), a gear pump, fed by an extruder e1, e2, should have pinions p1, p2, p3, p4 with a diameter of 50mm, a width of 175mm, with a notch rate of 20% maximum. A high rotation speed at 80 rpm (ie a tangential velocity of 210 mm / s in the case of the twin-screw extruder) would only give 11 kg / min. The average shear would be on the other hand 4 times higher, and in practice, one should limit the values of the flow rate to 5 kg / min to limit warming which is brought to degrade, even to vulcanize, a raw elastomer mixture. In addition, the gear pump involves side leaks or a tightness on the edges of the gears difficult to achieve given the operating pressures. This problem is solved in the case of a twin-screw extruder, since only the inlet side chamber is sealed to the outside (motor-reduction side).
    [041] More particularly, in the example illustrated in the figures, the twin-screw extruder 10 comprises two screws 11, 12 of parallel axes A-A 'and B-B' which are, in the example described, perpendicular to the X-X 'axis of the secondary extruder 40. The screws 11, 12 are arranged side-by-side in a housing which has an inner chamber 14 having a cross-section of eight. The screws 11, 12 each have a net of substantially rectangular section and constant over the length of the screw, they are arranged so as to mesh, the profiles of the two screws 11, 12 being conjugated. The profiles of the screws 11 and 12 thus have a very small clearance in the central region of the extruder 10, it includes a region close to a median longitudinal axis passing halfway between the axes A-A 'and B-B' so that the two screws are substantially gas-tight in this region, while they form C-shaped chambers with the periphery of the chamber 14. The rubber mix arrives through a central inlet port 16 from of the secondary extruder 40. The screws 11, 12 are rotated about their axes A-A 'and B-B' in opposite directions by a geared motor 15 with two output shafts each located in the extension of the axes A- A 'and B-B' to advance the rubbery mixture to the outlet of the extruder 10 through which it arrives in the channel 34.
    [042] Similarly to the previous one, the twin-screw extruder 20 comprises two screws 21, 22 of parallel axes C-C 'and D-D' which are, in the example described, perpendicular to the axis. Y-Y 'of the secondary extruder 50. The screws 21, 22 are arranged side by side in a housing which has an inner chamber 24 having an eight-shaped cross-section. The screws 21, 22 each have a net of substantially rectangular section and constant over the length of the screw, they are arranged so as to mesh, the profiles of the two screws 21, 22 being conjugated. The profiles of the screws 21 and 22 thus have a very low clearance in the central region of the extruder 20, it includes a region close to a median longitudinal axis passing halfway between the axes C-C 'and D-D' so that the two screws are substantially gas-tight in this region, while they form C-shaped chambers with the periphery of the chamber 24. The rubber mix arrives through a central inlet port 26 from of the secondary extruder 50. The screws 21, 22 are rotated about their axes C-C 'and D-D' in opposite directions by a geared motor 25 with two output shafts each located in the extension of the axes C- C 'and D-D' to advance the rubber mixture to the outlet of the extruder 20 through which it arrives in the channel 35.
    [043] FIGS. 3a and 3b illustrate two preferred embodiments of screw threads of twin-screw extruders 10, 20. The threads of the screws 11, 12 of FIG. 3a have a substantially trapezoidal shape with flanks 11a, 12a of concave shape. The threads of the screws 11, 12 of FIG. 3b have a substantially trapezoidal shape with convexly shaped flanks 11b, 12b. These threads ensure a better tightness of the C chambers and therefore a better performance of the twin-screw extruder.
    [044] The screws 11, 12 and 21, 22 of twin-screw extruders 10 and 20 are of the monofilet type or, alternatively they may have several nets. The nets preferably have a constant pitch. In a variant, for example when one wants to increase pressure, the pitch may be variable.
    [045] As best seen in FIG. 2, the first secondary extruder 40 and the first twin-screw extruder 10 are arranged in a common housing 40 '. As a result, the secondary extruder 40 works and pressurizes the first mixture A and then transfers it directly to the twin-screw extruder 10 via a central orifice 16. The same is true for the secondary extruder 50 and the second bi-screw extruder 20 which are arranged in a common housing 50 ', the pressure mixture being transmitted from the first to the second via the central orifice 26.
    [046] The two bi-screw extruders 10 and 20 are arranged in parallel while being juxtaposed (it is understood that they are on the same side, as seen with respect to a vertical plane passing through the outlet orifice 31) to converge in the profiling device 30. The coextruded profile P obtained by coextrusion through the profiling device 30 scrolls in the direction of the arrow F by being pulled by a motorized roller (not shown). In a variant, the profiling device cooperates with a rotary roller (not shown) on which the coextruded product P. is placed.
    [047] The installation also comprises a control unit 60 which is able to adjust the rotational speed of the screws 11, 12 and screws 21, 22 of the twin-screw extruders 10 and 20 as a function of the dimensions of the coextruded section P. The dimensions of the coextruded profile P, in particular the width and the thickness, are pre-established and measured using a sensor 70, for example an optical sensor. The sensor 70 is connected to the control unit 60 to which it transmits the measurement signal to allow the development of the dimensions of the profiling device at the beginning of operation. Once the focus is achieved, the sensor 70 verifies the dimensions of the coextruded profile and its compliance with predetermined dimensions. In one variant, a weight sensor measures the weight of the coextruded profile P and adjusts even more finely the tolerances of the coextruded product.
    [048] The control unit 60 operates, depending on the desired dimensions of the coextruded profile P or depending on the operating speed (variable speed, operating and stopping conditions) geared motors 15 and 25.
    [049] The bi-screw extruders 10 and 20 convey the mixture through the peripheral C-chambers so that the material contained in the chambers advance the value of the pitch of the thread per revolution. As a result, the adjustment of the rotational speed of the screws of each bi-screw extruder 10, 20 is directly proportional to the variation of its flow rate. This allows the control unit 60 to adjust the flow rate of each extruder depending on the dimensions of the coextruded product and also to keep it constant during operation.
    [050] The control unit 60 is also connected to the geared motors 44 and 54 of the secondary extruders 40 and 50 and is adapted to control the speed of rotation of the screws 42 or 52. This control is in synchronism with the control of the geared motors 15, 25, based on reports pre-established experimentally. In a variant, the rotational speed of the screws of the secondary extruders is based on the data received from the pressure sensors located in the vault of each secondary extruder.
    [051] The control unit 60 can also be connected to the drawing means of the coextruded profile strip P to adjust the speed.
    [052] Other variants and embodiments of the invention may be envisaged without departing from the scope of these claims.
    [053] Thus, the twin-screw extruder can be fed directly with a rubber mixture. For this, the screws are modified so as to have an inlet and feed portion which ensures the conveying and working of the mixture before arriving in the dosing chambers in C.
    [054] The installation of the invention may comprise several twin-screw extruders arranged in parallel to produce a coextruded profile product based on several uncured mixtures of different composition.
    [055] In a variant, the profiling device comprises one or more flow channels fed directly by a single-screw extruder and other channels fed by twin-screw extruders according to the invention.
    权利要求:
    Claims (11)
    [1" id="c-fr-0001]
    1) Extrusion installation for the manufacture of a coextruded profile P for tires made from rubber mixtures of different compositions, comprising a profiling device (30) arranged at the outlet of at least two flow channels (34,35) of rubber mixes of different composition, characterized in that said channels receive the mixtures from twin-screw extruders (10.20) counter-rotating interpenetrated nets and conjugate profiles.
    [0002]
    2) Installation according to claim 1, characterized in that each twin-screw extruder (10,20) is fed by a secondary extruder (40,50) with a single screw.
    [0003]
    3) Installation according to claim 2, characterized in that the twin-screw extruder (10.20) and the secondary extruder (40,50) are arranged in a common housing (40 ', 50').
    [0004]
    4) Apparatus according to claim 3, characterized in that the secondary extruder (40,50) has an outlet end (43,53) which communicates with a central inlet (16,26) in an internal chamber ( 14,24) of the twin-screw extruder (10,20).
    [0005]
    5) Installation according to one of claims 2 to 4, characterized in that the twin-screw extruder (10,20) and the secondary extruder (40, 50) each comprise its own drive means.
    [0006]
    6) Installation according to one of claims 2 to 5, characterized in that the axis of rotation (X-X '; Y-Y') of the screw of the secondary extruder (40,50) is transverse to the the axis of rotation (A-A ', B-B', C-C ', D-D') of the screws of the twin-screw extruder (10, 20).
    [0007]
    7) Installation according to one of the preceding claims, characterized in that it comprises a control unit (60) provided for adjusting the rotational speed of the screws of said twin-screw extruders (10,20) according to the dimensions of the profile coextruded.
    [0008]
    8) Installation according to claim 7, characterized in that said control unit (60) adjusts the rotation speed of the screws of said twin-screw extruders (10,20) to adapt to the operating conditions of an assembly line related.
    [0009]
    9) A method of manufacturing a coextruded P profile for tires made from rubber mixtures of different compositions by extrusion by passing through a profiling tool (30) from two flow channels (34,35) of mixture, characterized in that it comprises a step of supplying said channels made by twin-screw extruders (10,20) interpenetrating interpenetrated nets and conjugate profiles.
    [0010]
    10) A method according to claim 9, characterized in that it comprises a step of adjusting the rotational speed of the screws of the twin-screw extruder (10,20) as a function of dimensions of the coextruded section P.
    [0011]
    11) Method according to one of claims 9 or 10, characterized in that the flow rate provided by each twin-screw extruder (10, 20) is greater than 20kg / min for a speed less than or equal to 40tr / min.
    类似技术:
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    同族专利:
    公开号 | 公开日
    EP3393750A1|2018-10-31|
    FR3045441B1|2018-01-05|
    EP3393750B1|2021-11-24|
    WO2017109419A1|2017-06-29|
    US20180370074A1|2018-12-27|
    CN108463328A|2018-08-28|
    CN108463328B|2021-06-15|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP0091705A1|1982-04-01|1983-10-19|Gruptecnic S.A.|Extruding machine for plastic material and the like|
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    FR3084844B1|2018-06-27|2021-07-09|Michelin & Cie|EXTRUSION PLANT FOR TAPE OF ELASTOMERIC MIXTURES|
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    US20200198206A1|2018-12-19|2020-06-25|The Goodyear Tire & Rubber Company|Dual compound extruder apparatus with rotatable head|
    法律状态:
    2016-12-22| PLFP| Fee payment|Year of fee payment: 2 |
    2017-06-23| PLSC| Publication of the preliminary search report|Effective date: 20170623 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 3 |
    2019-09-27| ST| Notification of lapse|Effective date: 20190906 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1563085|2015-12-22|
    FR1563085A|FR3045441B1|2015-12-22|2015-12-22|INSTALLATION AND METHOD FOR EXTRUDING RUBBER MIXTURES|FR1563085A| FR3045441B1|2015-12-22|2015-12-22|INSTALLATION AND METHOD FOR EXTRUDING RUBBER MIXTURES|
    PCT/FR2016/053623| WO2017109419A1|2015-12-22|2016-12-21|Apparatus and method for extruding rubber mixtures|
    EP16831504.2A| EP3393750B1|2015-12-22|2016-12-21|Apparatus and method for extruding rubber mixtures|
    US16/064,801| US11279060B2|2015-12-22|2016-12-21|Apparatus and method for extruding rubber mixtures|
    CN201680075164.8A| CN108463328B|2015-12-22|2016-12-21|Device and method for extruding a rubber mixture|
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